Travis Ancelet†‡*, Perry K. Davy†, Tamsin Mitchell§, William J. Trompetter†, Andreas Markwitz†, and David C. Weatherburn‡
† GNS Science, 30 Gracefield Road, PO Box 31312, Lower Hutt, New Zealand
‡ School of Chemical and Physical Sciences, Victoria University of Wellington, PO Box 600, Wellington, New Zealand
§ Greater Wellington Regional Council, 142 Wakefield Street, PO Box 11646, Wellington, New Zealand
Environ. Sci. Technol., Article ASAP
Publication Date (Web): April 2, 2012
Copyright © 2012 American Chemical Society
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Particulate matter (PM) sources at two different sites in a rural town in New Zealand were investigated on an hourly time-scale. Streaker samplers were used to collect hourly, size-segregated PM10–2.5 and PM2.5 samples that were analyzed for elemental content using ion beam analysis techniques. Black carbon concentrations were determined using light reflection and PM10 concentrations were recorded using colocated continuous PM monitors. PM10 concentrations at both sites displayed a diurnal pattern, with hourly PM10 concentration maxima in the evening (7 pm–midnight) and in the morning (7–9 am). One of the monitoring sites experienced consistently higher average PM10 concentrations during every hour and analysis indicated that katabatic flows across the urban area contributed to the increased concentrations observed. Source apportionment using positive matrix factorization on the hourly data revealed four primary PM10 sources for each site: biomass burning, motor vehicles, marine aerosol and crustal matter. Biomass burning was the most dominant source at both sites and was responsible for both the evening and morning PM10 concentration peaks. The use of elemental speciation combined with PM10 concentrations for source apportionment on an hourly time-scale has never been reported and provides unique and useful information on PM sources for air quality management.